Phase Transitions in the Alkali C1 —n. C4 Alkanoates

Author:

Ferloni P.1,Sanesi M.1,Franzosini P.1

Affiliation:

1. Centro di studio per la termodinamica ed elettrochimica dei sistemi salini fusi e solidi del CNR c/o Istituto di Chimica Fisica e di Elettrochimica della Universitä, Pavia (Italy)

Abstract

The enthalpies and entropies of fusion and of solid state transitions in Li formate and acetate; Li, Na, K, Rb, Cs propionates; Li, Rb, Cs n.butyrates were determined by differential scanning calorimetry. Supplementary information was provided through conductance measurements on solids. The collected data, together with those from previous papers, allowed to give a picture of the thermal behaviour of the alkali C1-n. C4 alkanoates. Heat capacity data on solid and molten Na formate, acetate and propionate were also determined

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

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