Affiliation:
1. Universität Konstanz, Fachbereich Chemie
Abstract
Abstract
A formalism is presented to obtain approximate analytic expressions for the eigenstates and eigenvalues of a quantum double oscillator (QDO). The matrix elements of a large class of operators with respect to states of different double oscillators result as finite sums of explicit functions of the respective parameters. Matrix elements between states of a harmonic oscillator and a double oscillator are also determined. The analytic expressions were used to calculate Franck-Condon factors for electronic transitions including double oscillator anharmonicities.
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics
Cited by
14 articles.
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