The Thermoelectric Power of the Molten Systems (Ag+Li)NO3, (Ag+Na)NO3, and (Ag+K)NO3

Author:

Sinistri Cesare1

Affiliation:

1. Institute of Physical Chemistry, University of Pavia, Italy

Abstract

In a silver electrodes thermocell the thermoelectric power ε0 at zero time of the molten salt mixtures (Ag+Li)NO3 and (Ag+Na)NO3 at the mean temperature of 340 °C, and of (Ag+K)NO3 at the mean temperature of 360 °C has been measured. On the basis of these data the transport heats of lithium, sodium and potassium ions in their respective pure nitrates have been roughly evaluated. Moreover a thermodynamical ideal model for the molten salt mixtures in respect to the transport properties is suggested.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

Cited by 9 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Estimation of single electrode heats;Electrochimica Acta;1998-06

2. Agi-Ag oxysalt glasses: review of thermodynamic and transport properties;Materials Chemistry and Physics;1989-08

3. Soret Coefficients and Transported Entropies of Nonisothermal Liquid Alkali Nitrate + Silver Nitrate Mixtures;Berichte der Bunsengesellschaft für physikalische Chemie;1982-01

4. The thermal emf of alkali metal—molten salt mixtures;Electrochimica Acta;1977-09

5. Thermal diffusion in ionic melts;Electrochimica Acta;1977-09

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