Author:
Macarie Lavinia,Plesu Nicoleta,Iliescu Smaranda,Ilia Gheorghe
Abstract
Abstract
Organophosphorus chemistry was developed in the last decade by promoting the synthesis reactions using ionic liquids either as solvent or catalyst. Ionic liquids (ILs), the so-called “green solvents”, have gained interest in the synthesis of organophosphorus compounds as alternatives to flammable and toxic organic solvents and catalysts. ILs have beneficial properties because they provide high solubility for many organic and inorganic compounds or metal complexes, have no vapor pressure, and are reusable. Also, in some cases, they can enhance the reactivity of chemical reagents. In this review, we aimed at showing the synthesis of different organophosphorus compounds under green and mild conditions using ILs as reaction media or catalysts, according to a trend developed in the last years. A novel trend is to perform these syntheses under microwave irradiation conditions together with ILs as solvents and catalysts.
Subject
General Chemical Engineering
Reference142 articles.
1. Benzimidazolium dicationic ionic liquid as an efficient and reusable catalyst for the synthesis of α-aminophosphonates and bis(α-aminophosphonates) under solvent-free condition;Phosphorus Sulfur Silicon,2015
2. Efficient synthesis of α-aminophosphonates via one-pot reactions of aldehydes, amines, and phosphates in ionic liquid;Heteroatom Chem,2011
3. Chemistry of the 4,6-dioxo-1,3,5,2λ3-triazaphosphinanes, part III.: synthesis of 4,6-dioxo-1,3,5,2λ3-, 4,6-dioxo-1,3,5,2λ4-, and 4,6-dioxo-1,3,5,2λ5-triazaphosphinanes;Z Naturforsch,1993b
4. Synthesis, characterization and properties of novel cellulose derivatives containing phosphorus: cellulose diphenyl phosphate and its mixed esters;Cellulose,2014
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