Synthesis, Vibrational Spectra and Normal Coordinate Analysis of Cesium-Hexathiohypodiphosphate Cs4P2S6-Reference-Cited by-同舟云学术

Synthesis, Vibrational Spectra and Normal Coordinate Analysis of Cesium-Hexathiohypodiphosphate Cs4P2S6

Published:1985-07-01 Issue:7 Volume:40 Page:709-713
ISSN:1865-7109
Container-title:Zeitschrift für Naturforschung A
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Author:

Cyvin S. J.¹,Cyvin B. N.¹,Wibbelmann C.²,Becker R.³,Brockner W.³,Parensen M.³

Affiliation:

1. 1Institutt for fysikalsk kjemi, Norges tekniske høgskole, N-7034 Trondheim-NTH, Norway

2. 2Department of Chemistry, University of Aberdeen, Old Aberdeen, AB 9 2UE, Scotland

3. 3Institut für Anorganische Chemie, Technische Universität Clausthal, D-3392 Clausthal-Zellerfeld, FRG

Abstract

The title compound has been prepared by elemental synthesis at high temperatures and also by reaction of Na4P2S6 · 6H2O with CsCl in aqueous solution. Both reaction products have closely related vibrational spectra which are assigned on the basis of a P2S64- anion with perturbed D3d symmetry. A normal coordinate analysis has been performed using a force Field with 4 initial force constants. The refined force Field, potential energy distribution (PED), mean amplitudes of vibration and Coriolis coupling constants are given.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

Link

https://www.degruyter.com/document/doi/10.1515/zna-1985-0710/pdf

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