{K-[2 2 2]-Crypt}2Se7·H20; Synthese, IR-Spektrum und Kristallstruktur-Reference-Cited by-同舟云学术

{K-[2 2 2]-Crypt}2Se7·H20; Synthese, IR-Spektrum und Kristallstruktur

Published:1991-01-01 Issue:1 Volume:46 Page:63-67
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Müller Volker¹,Dehnicke Kurt¹,Fenske Dieter²,Baum Gerhard²

Affiliation:

1. Fachbereich Chemie der Universität Marburg, Mans-Meerw ein-Straße, D-3550 M arburg/Lahn

2. Institut für Anorganische Chemie der Universität Karlsruhe, Engesserstraße, D-7500 Karlsruhe

Abstract

{K-[2 2 2]-Crypt}2Se7·H20 has been prepared by the reaction of a solution of potassium polyselenide in dimethylformamide at room temperature as black crystals, which were characterized by IR spectroscopy as well as by an X-ray structure determination. Space group P21/n, Z = 4, 5055 observed unique reflexions, R = 0.103. Lattice dimensions at 20 °C: a = 1435(1), b = 1320(1), c = 2966(2) pm, β = 102.50(6)° The heptaselenide ion represents approximately part of a helical chain of polymeric selenium.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1991-0114/pdf

Cited by 23 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Polychalcogen molecules, ligands, and ions Part 2: Catenated acyclic molecules, ions, and p-block element derivatives;Comprehensive Inorganic Chemistry III;2023

2. Catenated Compounds: Group 16 Elements Selenium and Tellurium;Reference Module in Chemistry, Molecular Sciences and Chemical Engineering;2019

3. Organic Cation and Complex Cation-Stabilized (Poly-)Selenides, [Cation]x(Sey)z: Diversity in Structures and Properties;Zeitschrift für anorganische und allgemeine Chemie;2014-11

4. Catenated Compounds – Group 16 (Se, Te);Comprehensive Inorganic Chemistry II;2013

5. Polychalcogenide Anions: Structural Diversity and Ligand Versatility;Zeitschrift für anorganische und allgemeine Chemie;2012-08-24