Affiliation:
1. Laboratorium für Anorganische Chemie der Universität Bayreuth, Postfach 101251, D-8580 Bayreuth
2. Department of Chemistry, The University of Calgary, Calgary T 2 N 1 N 4 , Alberta, Canada
Abstract
The metathetical reactions of potassium thionylimide, KNSO, with arsenic and antimony halides in acetonitrile solution have been used to prepare two series of arsenic and antimony thionylimides, tBu3-nAs(NSO)n and tBu3-nSb(NSO)n, respectively, (n = 3, 2, 1). The tert-butyl- substituted compounds are moisture-sensitive oils. The half-sandwich hydrido-metal complexes CpM(CO)3H react with tBuAs(NSO)2 in THF solution to give the metallo-arsanes [Cp(CO)3M]As(tBu)(NSO) (M = Cr, M o, W).
Cited by
4 articles.
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