Synthese und Röntgenstrukturanalyse einer acyclischen Schwefel-Stickstoff-Verbindung mit einer S5N4-Kette / Synthesis and X-Ray Structural Analysis of an Acyclic Sulfur Nitrogen Compound with an S4N5 Chain

Abstract

The title compound was obtained on reduction of R2S4N3 +Cl- via dismutation. Its crystal structure was determined by X-ray diffraction. (CH3-C6H4)2-S5N4: The conformation of the SN chain closely resembles that of (SN)x; however, the bond-distances are in accordance with the assumption of alternating S(II) and S(IV) atoms.