Notizen: Reaktionen von Me2NC(S)SN(SiMe3)2 mit Metallhalogeniden — Kristallstruktur von Me2NCS2ZrCl3 · 3 Pyridin / Reactions of Me2NC(S)SN(SiMe3)2 with Metal Halides – Crystal Structure of Me2NCS2ZrCl3

Notizen: Reaktionen von Me2NC(S)SN(SiMe3)2 mit Metallhalogeniden — Kristallstruktur von Me2NCS2ZrCl3 · 3 Pyridin / Reactions of Me2NC(S)SN(SiMe3)2 with Metal Halides – Crystal Structure of Me2NCS2ZrCl3 · 3 Pyridine

Published:1991-08-01 Issue:8 Volume:46 Page:1117-1121
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Roesky Herbert W.¹,Meller-Rehbein Birgit¹,Noltemeyer Mathias¹

Affiliation:

1. Institut für Anorganische Chemie der Universität, Tamannstraße 4, D-3400 Göttingen

Abstract

Me2NC(S)SN(SiMe3)2 (1) reacts with TeCl4 and NbCl5 to yield Me2NC(S)SNTeCl2 (4) and Me2NC(S)SNNbCl3 (5), while the dithiocarbamate complexes 6 and 7 are formed with ZrCl4 and HfCl4. The crystal structure of 6 is reported. The reaction of Me2NC(S)SN=TiCl2·3 py 2 with LiN(SiMe3)2 gives the tricyclic compound 8.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1991-0824/pdf

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