Elektronenbeugungsmessungen zur Struktur des Methoximethylphosphorylfluorids / Electron Diffraction Investigations of the Structure of Methoxi-methyl-phosphoryl-fluoride

Abstract

The structure of Methoxi-methyl-phosphoryl-fluoride has been investigated by electron diffraction on gases. The bond distance of the P-F bond (1.536 Å) corresponds with the value given by Kuchitsu for OPF3 (1.523 ±0.003 Å). The P = O distance is remarkable longer than the value given by Kuchitsu, but corresponds to a value given by Oberhammer for the molecule OP (OCH3)3.