Zur Analyse der Rotationsspektren in torsionsangeregten Zuständen von Molekülen mit zwei Methylgruppen/A Contribution to the Analysis of Rotational Spectra in Torsional Excited States of Molecules with two Methyl Tops-Reference-Cited by-同舟云学术

Zur Analyse der Rotationsspektren in torsionsangeregten Zuständen von Molekülen mit zwei Methylgruppen/A Contribution to the Analysis of Rotational Spectra in Torsional Excited States of Molecules with two Methyl Tops

Published:1973-05-01 Issue:5 Volume:28 Page:750-758
ISSN:1865-7109
Container-title:Zeitschrift für Naturforschung A
language:en
Short-container-title:

Author:

Trinkaus A.¹,Dreizier H.¹²,Rudolph H. D.¹

Affiliation:

1. Physikalisches Institut der Universität Freiburg

2. Neue Anschrift: Institut für Physikalische Chemie, Abt. Chemische Physik, D-2300 Kiel, Olshausenstraße 40/60.

Abstract

An analysis of the rotational spectra in torsional excited states is given for propane, dimethylsilane and dimethylsulfide. The analysis is based on the Hamiltonian for the quasi-rigid model. The potential barrier V3 and one additional potential coefficient V′12 were determined. The splitting within the multipletts could be reproduced, but not the spacing between them.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

Link

https://www.degruyter.com/document/doi/10.1515/zna-1973-0536/pdf

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