Affiliation:
1. Pharmazeutisches Institut der Universität Freiburg i. Br.
2. Institut für Elektrowerkstoffe der Fraunhofer-Gesellschaft Freiburg i. Br.
Abstract
The configurations of some 2,6-diaryl-1-oxa- and 1-thiocyclohexanones (cis and trans) have been confirmed by p. r. spectroscopy. The conformations of these ketones are discussed. Reaction with sodium borohydride performs two epimeric alcohols from the cis-ketones, whereas each trans-ketone yields only one reduction product. The configurations of the alcohols have been determined by p. r. spectroscopy. In all these alcohols, the heterocyclic ring exists very probably in the chair conformation.
Cited by
11 articles.
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