Synthesis structural optical and mechanical properties of Nb3⁺ doped Zinc Borophosphate glass for radiation shielding application

Author:

Vinothkumar Panjanathan1,Priyadharshini Elumalai2,Praveenkumar Sukumar3,Sathiyamurthy Subbarayan4,Mani Kailasam Saravana56,Ayyar Manikandan56,Hashem Mohamed7,Fouad Hassan8,Ansari AbuZar9

Affiliation:

1. Department of Physics , Saveetha Engineering College , Thandalam , Chennai 602 105 , India

2. Department of Physics , Velammal Institute of Technology , Panchetti , Chennai 601204 , India

3. Department of ECE , Saveetha Engineering College , Thandalam , Chennai 602 105 , India

4. Department of Automobile Engineering , Easwari Engineering College , Chennai 600089 , Tamil Nadu , India

5. Department of Chemistry , Karpagam Academy of Higher Education , Coimbatore 641 021 , Tamil Nadu , India

6. Centre for Material Chemistry , Karpagam Academy of Higher Education , Coimbatore 641 021 , Tamil Nadu , India

7. Department of Dental Health, College of Applied Medical Sciences , King Saud University , P.O Box. 12372 , Riyadh , Saudi Arabia

8. Biomedical Engineering Department, Faculty of Engineering , Helwan University , Helwan , Egypt

9. Department of Obstetrics and Gynecology and Ewha Medical Research Institute, College of Mediciane , Ewha Womens University , Seoul 07984 , Republic of Korea

Abstract

Abstract The Nb3⁺ doped Zinc Borophosphate glass (30B2O3 +35P2O5+5TiO2+10ZnO+9LiCO3+10 BaCO3+1NbO2) has been synthesized successfully using melt-quenching method. The powder X-ray diffraction (XRD) analysis was used to find the glass nature of Nb3⁺ doped Zinc Borophosphate glass. The functional group of Nb3⁺ doped Zinc Borophosphate glass was recognized using Fourier-transform infrared spectroscopy (FTIR) analyses. Linear optical properties of the Nb3⁺ doped Zinc Borophosphate glass were studied using UV–vis–NIR spectrum in the room temperature. Mechanical behaviour of Nb3⁺ doped Zinc Borophosphate glass was examined through Vicker’s hardness method. The mechanical properties of Nb3⁺ doped Zinc Borophosphate glass was examined with various loads. The emission transitions of Nb3⁺ doped Zinc Borophosphate glass was studied using Photoluminescence analysis. The CIE diagram of the Photoluminescence was examined. Gamma ray shielding parameters such half value layer, mean free path and mass attenuation coefficient of Nb3⁺ doped Zinc Borophosphate glass were studied using Phy-X software.

Funder

King Saud University, Riyadh, Saudi Arabia

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry

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