Potential applications of low-cost Brazilian corn starch as an adsorbent for removing the Acid Violet 19 contaminant from river water
Author:
do Rêgo Júnior Alrivan Gomes1, de Oliveira Íngride Pamilly Ribeiro Araújo1, de Souza Joalis Barbalho1, da Fonsêca Melo Tereza Noêmia Tavares1, da Silva Vieira Ricardo Alan1, dos Santos Souza Ytalo Cleyton1, de Souza Xavier Moizes1, de Queiroz Lucas Rego1, Sales Alves Jose Irlandio1, de Menezes Francisco Leonardo Gomes1ORCID, Júnior Francisco Franciné Maia1, Khan Sabir1
Affiliation:
1. Department of Natural Sciences , Mathematics and Statistics , Federal University of the Semi-Arid , 59625-900 Mossoró , RN , Brazil
Abstract
Abstract
Indeed, the textile dye industry has a significant impact on the global economy, as it is an integral part of the textile and fashion industries. However, this advancement has become a great concern with industrial waste, a good part of these dyes have toxic characteristics to the environment and living beings. The objective of this work is the use of local corn starch as an adsorbent, for the removal of acid violet (AV19), a dye that is highly toxic and carcinogenic in real water samples. The material was characterized by scanning electron microscopy (SEM) and infrared (IR). The optimized parameters were concentration, time, and pH, in which the best results will be obtained at 60 min and pH 7. The experiment was compared to the Langmuir, Freundlich, and Temkin models. The concentration of dye was 4 mg L−1 had the highest removal which was 84.46 %. The prim rate constant is k′ = 0.8592 therefore the adsorption system studied obeys the pseudo-second-order kinetic model. In the next step, we will apply the top-performing starch to environmental samples containing the investigated dye. An analytical curve was constructed in the 2–14 ppm range at a maximum wavelength of 590 nm. The detection limit was 0.541 mg/L, and the percentage recovery was obtained in the range of 95–99.8 % for real water samples.
Publisher
Walter de Gruyter GmbH
Subject
Physical and Theoretical Chemistry
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