Development of green and sustainable corrosion inhibitor for steel rebar in chloride-polluted simulated concrete pore solution using seed extract of Psoralea corylifolia (Badranj Boya)

Author:

Singh Ambrish1,Ansari Kashif R.2,Ali Ismat H.3,Alanazi Abdullah K.4,Lin Yuanhua2,Al-Moubaraki Aisha H.5

Affiliation:

1. Department of Chemistry , Nagaland University , Lumami , Zunheboto 798627 , Nagaland , India

2. State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation , Southwest Petroleum University , Chengdu , Sichuan 610500 , China

3. Department of Chemistry, College of Science , King Khalid University , Abha , P.O. Box 9004 , Saudi Arabia

4. Department of Chemistry, College of Science , Taif University , P.O. Box 11099 , Taif 21944 , Saudi Arabia

5. Chemistry Department, Faculty of Science–Alfaisaliah Campus , University of Jeddah , Jeddah , Saudi Arabia

Abstract

Abstract The present research aims to develop green and sustainable corrosion inhibitors based on plant extract. Herein, we have screened the inhibitory performance of Psoralea corylifolia (Badranj Boya) (PCS) seeds in chloride-polluted simulated concrete pore solution (SCPS) for the protection of steel rebar. Electrochemical experiments manifest that PCS can restrain reactions of the cathode and anode of steel rebar. The results reveal that the inhibitory performance magnitude is 95.1 % at 75 mg/L dosing amount after 72 h dipping time. Scanning electron microscopy (SEM) and Atomic force microscopy (AFM) examination support the creation of an inhibitive layer of PCS over the steel rebar surface. Furthermore, adsorbed PCS over the steel rebar was justified via X-ray photoelectron spectroscopy (XPS). Finally, PCS is a green and long-term efficient corrosion inhibitor for concrete structures.

Funder

King Khalid University

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry

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