Experimental insights into the adsorption of newly synthesized Gemini ethoxylated surfactant on C-steel in different acidic media accompanied by DFT and MCs studies
Author:
El Basiony Nasser M.12, Elsharaky Elsayed A.1, Kim Dong-Hwan2, El-Tabei Aziza S.1
Affiliation:
1. Egyptian Petroleum Research Institute (EPRI) , Nasr City 11727 , Cairo , Egypt 2. School of Chemical Engineering , Sungkyunkwan University , Suwon 16419 , Republic of Korea
Abstract
Abstract
Bis ethoxylated cationic surfactant (BOECS) is synthesized. The prepared surfactant’s structure configuration was verified through a variety of spectral and physicochemical techniques, including FT-IR, MS,1HNMR, and surface activity evaluations. BOECS applications as a C-steel corrosion inhibitor in 1.0 N HCl and 1.0 N H2SO4 and sulfate reducing bacteria (SRB) mitigations have been investigated thoroughly. Physical properties of the BOECS indicate its potential adsorption affinity at the air/water interface. The electrical conductivity determines the CMC value in accordance with the surface tension value. Electrochemical kinetic parameters indicate the BOECS is sorted as a mixed-type inhibitor and has an inhibition efficacy of 91.22 % and 81.26% for HCl and H2SO4, respectively. Active centers of BOECS structure enhance its adsorption at the electrolyte/C-steel. Calculated adsorption energy change (∆G
ads) and theoretical adsorption energy (E
ads) values suggest strong and spontaneous BOECS adsorption. The cytotoxic performance of the synthesized BOECS exhibited a potent inhibitory potential against the SRB. The outcomes of this research exhibit that the BOECS can lower SRB growth from 106 to 102 cell/mL.
Funder
National Research Foundation of Korea
Publisher
Walter de Gruyter GmbH
Subject
Physical and Theoretical Chemistry
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