Author:
Sharma Nivedita,Bansal Raj K.
Abstract
Abstract
1,3-Azaphospholo[1,5-a]pyridines named as 2-phosphaindolizines were obtained from [4+1] cyclocondensation and 1,5-electrocyclization methods. These compounds incorporate several reactive functionalities and undergo electrophilic substitution, Diels-Alder reaction and 1,2-addition with hydrogen sulfide and sulfur across the >C=P– functionality and form η1-P coordination compounds with metal carbonyls. Thus, 2-phosphaindolizines could be used as precursors for accessing a variety of organophosphorus compounds.
Subject
General Chemical Engineering,General Chemistry
Cited by
2 articles.
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