Efficient modular phosphorus-containing ligands for stereoselective catalysis

Author:

Llorente Nuria12ORCID,Fernández-Pérez Héctor1ORCID,Núñez-Rico José L.1ORCID,Carreras Lucas12ORCID,Martínez-Carrión Alicia12ORCID,Iniesta Ester12ORCID,Romero-Navarro Andrés12ORCID,Martínez-Bascuñana Alba12ORCID,Vidal-Ferran Anton13ORCID

Affiliation:

1. Institute of Chemical Research of Catalonia (ICIQ) and The Barcelona Institute of Science and Technology (BIST) , Av. Països Catalans 16 , Tarragona 43007 , Spain

2. Universitat Rovira i Virgili , Departament de Química Analítica i Química Orgànica , c/Marcel·lí Domingo, 1 , Tarragona 43007 , Spain

3. ICREA , Pg. Lluís Companys 23 , Barcelona 08010 , Spain

Abstract

Abstract Over several years, our research team has contributed to ligand design for metal-catalyzed stereoselective transformations. This has been achieved with the synthesis and application to organic transformations of interest of an array of structurally diverse P-containing ligands. These range from highly modular enantiopure phosphine–phosphite ligands to supramolecularly regulated enantioselective phosphorus-based catalysts. Our research in supramolecular interactions has also led to the discovery of an unprecedented halogen-bonded rhodium-catalyst.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Reference96 articles.

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3. I. Ojima. Catalytic Asymmetric Synthesis, 3rd ed., p. 998, John Wiley & Sons Ltd., Chichester (2010).

4. H. Yamamoto, E. Carreira. Comprehensive Chirality, p. 5648, Elsevier, Oxford (2012).

5. A. Börner. Phosphorus Ligands in Asymmetric Catalysis, p. 1546, Wiley-VCH, Weinheim (2008).

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