Nomenclature for boranes and related species (IUPAC Recommendations 2019)

Author:

Beckett Michael A.1ORCID,Brellochs Bernd2,Chizhevsky Igor T.3,Damhus Ture4,Hellwich Karl-Heinz5ORCID,Kennedy John D.67ORCID,Laitinen Risto8,Powell Warren H.9,Rabinovich Daniel10,Viñas Clara11ORCID,Yerin Andrey12ORCID

Affiliation:

1. School of Chemistry, Bangor University , Bangor , UK

2. Boron Hydride Highlights , Neufahrn , Germany

3. INEOS, Russian Academy of Sciences , Moscow , Russia

4. Østerbro , Copenhagen , Denmark

5. Beilstein-Institut zur Förderung der Chemischen Wissenschaften , Frankfurt , Germany

6. School of Chemistry, The University of Leeds , Leeds , UK

7. The Institute of Inorganic Chemistry of the Czech Academy of Sciences , Řež u Prahy , The Czech Republic

8. Oulu University , Oulu , Finland

9. Columbus, OH , USA

10. University of North Carolina , Department of Chemistry , Charlotte, NC , USA

11. Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC) , Bellaterra , Spain

12. Advanced Chemistry Development , Moscow , Russia

Abstract

Abstract An appraisal of the current IUPAC recommendations for the nomenclature of boranes and related systems has been undertaken. New developments in the field have been investigated and existing nomenclature systems have been adapted to accommodate these new developments. The principal areas considered are stoichiometric and structural nomenclature (including heteroatom and metal-atom subrogation, as well as substitution of hydrogen), conjoined-cage species, supra-icosahedral systems, and sub-icosahedral non-standard structures. Elements of substitutive, additive, and replacement nomenclature systems have been integrated into individual names to address contentious problems in boron nomenclature that have been around for a long time.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Reference39 articles.

1. IUPAC. Nomenclature of Inorganic Chemistry, IUPAC Recommendations 2005, N. G. Connelly, T. Damhus, R. M. Hartshorn, A. T. Hutton (Eds.), RSC Publishing, Cambridge, UK (2005); (a) IR-6, pp. 83–110; (b) IR-6.2.3.1, pp. 89–90; (c) IR-9.2.4.2, pp. 155–160; (d) IR-10.2.3.3, pp. 210–211; (e) Table VI, p. 260; (f) Table X pp. 337–339.

2. IUPAC. Nomenclature of Inorganic Chemistry, Recommendations 1990, G. J. Leigh (Ed.), Blackwell Scientific Publications, Oxford, UK (1990); (a) I-11, pp. 207–237; (b) pp. xx–xxi; (c) I-11.3.2.1, p. 217; (d) I-11.3.1.2, pp. 211–214; (e) I-11.3.2.5, p. 224; (f) I-11.3.2.3, pp. 222–223; (g) I-11.3.1.2, pp. 212–213; (h) I-11.3.2.4, pp. 223–224; (i) I-11.4.2, pp. 227–228; (j) I-11.4.3.1, p. 228; (k) I-11.4.3.3, pp. 231–232; (l) I-11.4.3.2, pp. 228–230; (m) I-11.4.3.3, note 11o, p. 231; (n) I-11.5.2, p. 233; (o) I-11.3.1.2, pp. 215–217; (p) I-11.3.2.7, pp. 224–225.

3. R. M. Adams. Pure Appl. Chem. 30, 681 (1972).

4. IUPAC. Nomenclature of Inorganic Chemistry Definitive Rules 1970, 2nd ed., Butterworth and Co, London (1971) Chapter 11, (a) pp. 92–97; (b) p. 96; (c) p. 97; (d) pp. 93–94.

5. K. Wade. Adv. Inorg. Chem. Radiochem. 18, 1 (1976).

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