Untersuchungen an Polyhalogeniden, XXXIV Cäsium(18-Krone-6)dichloroiodat, [Cs(C12H24O6)]ICl2/Studies on Polyhalides, XXXIV Cesium (18 -crown -6 )dichloroiodate, [Cs(C12H24O6)]ICl2

Author:

El Essawi Mervat1,Tebbe Karl-Friedrich2

Affiliation:

1. Chemical Department, Faculty of Science, Cairo University, Giza, Egypt

2. Institut für Anorganische Chemie der Universität zu Köln, Greinstraße 6 , D-50939 Köln

Abstract

Abstract The new compound [Cs(18-crown-6)]ICl2 has been prepared by the reaction of cesium chloride and 18-crown-6 with iodine chloride in ethanol and structurally characterized by X-ray diffrac­tion methods. The geometries of the cation [Cs(18-crown-6)]+ and of the anion ICl2 - are as expected.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

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