Oxochlorierung von Übergangsmetall-Komplexen mit Thionylchlorid/Oxochlorination of Transition Metal Complexes with Thionyl Chloride-Reference-Cited by-同舟云学术

Oxochlorierung von Übergangsmetall-Komplexen mit Thionylchlorid/Oxochlorination of Transition Metal Complexes with Thionyl Chloride

Published:1998-02-01 Issue:2 Volume:53 Page:153-156
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Stoll Carola¹,Lorenz Ingo-Peter¹,Nöth Heinrich¹,Seifert Thomas¹

Affiliation:

1. Institut für Anorganische Chemie der Ludwig-Maximilians-Universität München, Meiserstr. 1, D-80333 München

Abstract

Abstract The reaction of the transition metal complexes CpV(CO)4 and [CpMo(CO)3]2 with thionyl chloride affords the oxodichlorides CpM(O)Cl2 (M = V, Mo) by oxidative decarbonylation. The X-ray structure analysis of CpV (O)Cl2 shows the pseudo tetrahedral “piano-stool” configuration for the central vanadium atom.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1998-0204/pdf

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