Affiliation:
1. College of Pharmacy, Jiangxi University of Traditional Chinese Medicine , Nanchang 330004 , P.R. China
Abstract
Abstract
A new multicage compound [(Me)2EtNH][Mn(N3)3] (Me = methyl, Et = ethyl) with a perovskite-related structure has been synthesized. The manganese(II) cations are bridged by end-to-end (EE) azide anions to form three-dimensional cages with the N,N-dimethylethylammonium cations residing in the cavities of the [Mn(N3)3]
n
n
− cages. The compound has been characterized by single-crystal X-ray diffraction, IR spectroscopy, elemental analysis, second-harmonic generation, and magnetic measurements. The second-harmonic generation results support its noncentrosymmetric polar crystal structure. Magnetic susceptibility measurements show antiferromagnetic interactions among the MnII ions.
Funder
Doctoral Research Starting Foundation for Jiangxi University of Traditional Chinese Medicine
Jiangxi Science and Educational Committee
National Natural Science Foundation of China
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