Affiliation:
1. Institute of Molecular Engineering and Applied Chemistry , Anhui University of Technology , Ma’anshan , Anhui 243002 , P.R. China
Abstract
Abstract
Treatment of cis-[RuCl2(phen)2]·2H2O (phen=1,- 10-phenanthroline) with 1-(2,6-diisopropylphenoxy)-4-phenylphthalazine (HL1) or 1-(2,6-dimethylphenoxy)-4-phenylphthalazine (HL2) in the presence of AgPF6 afforded two cyclometalated ruthenium(II) complexes, [Ru(κ
2-C,N-L1)(phen)2](PF6) (1) and [Ru(κ
2-C,N-L2)(phen)2](PF6) (2), respectively. The two complexes have been characterized by UV–vis and luminescence spectroscopy. The structure of 1·1.5H2O has been determined by single-crystal X-ray diffraction.
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