Affiliation:
1. Institute of Molecular Engineering and Applied Chemistry , Anhui University of Technology , Ma’anshan, Anhui 243002 , P.R. China
Abstract
Abstract
Interaction of (NH4)6Mo7O24·4H2O with tris-(3,5-di-tert-butyl-2-hydroxy-benzylidene)triaminoguanidinium chloride [H6
t
Bu6L]Cl in DMF-H2O resulted in isolation of a neutral dinuclear Mo(VI) complex [Mo2O4(OH2)(DMF)(H
t
Bu6L)]·3DMF. The C
3-symmetric-type ligand H
t
Bu6L is coordinated to two cis-{MoO2}2+ moieties via phenolic-oxygen, guanidine nitrogen and azomethine nitrogen atoms, and the remaining sixth coordination sites of the molybdenum centers are occupied by the oxygen atoms from the solvent molecules.