Synthesis, crystal structure, and magnetic properties of the complex [(CH3)3NH]2 [Co(NCS)4]

Author:

Jie Yang1,Yuan Huang1,YouQuan Zhong1,Ting Fang1,Fan Hao1,Qian Kun1,Ye Yao-Hui2

Affiliation:

1. College of Pharmacy, Jiangxi University of Traditional Chinese Medicine , Nanchang 330004 , P.R. China

2. Administration Office, Jiangxi University of Traditional Chinese Medicine , Nanchang 330004 , P.R. China

Abstract

Abstract A new complex [(CH3)3NH]2[Co(NCS)4], in which zero-dimensional [Co(NCS)4] n 2− anions are balanced by 2n [(CH3)3NH]+ cations, was synthesized. The complex has been characterized by single X-ray diffraction, infrared spectroscopy, elemental analysis, and magnetic measurements. Magnetic susceptibility data indicate ferromagnetic interactions among the CoII ions.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

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