A zinc(II) coordination polymer containing single- and double-stranded helical chains: synthesis, crystal structure, and thermal and luminescence properties

Author:

Zhang Fei-Hang1,Chai Nan-Nan1,Chen Sheng-Chun2,He Ming-Yang1,Chen Qun1

Affiliation:

1. Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering , Changzhou University , Changzhou 213164 , P.R. China

2. Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering , Changzhou University , Changzhou 213164 , P.R. China , Fax: +8651986330251

Abstract

Abstract A new zinc(II)-based coordination polymer {[Zn(5-fip)(tdbpy)]·(DMF)} n (1) {5-H2fip=5-fluoroisophthalic acid, tdbpy=4,4′-(2,4,8,10-tetraoxaspiro[5.5]undecane-3,9-diyl)bispyridine, DMF=dimethylformamide} has been solvothermally synthesized and structurally characterized. Single-crystal X-ray diffraction revealed that complex 1 shows a unique two-dimensional network architecture containing single-stranded [Zn(5-fip)] n and double-stranded helical [Zn(tdbpy)] n chains. The thermal and luminescence properties of complex 1 have also been studied.

Funder

National Natural Science Foundation of China

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Reference34 articles.

1. H.-C. Zhou, S. Kitagawa, Chem. Soc. Rev.2014, 43, 5415.

2. K. Sumida, D. L. Rogow, J. A. Mason, T. M. McDonald, E. D. Bloch, Z. R. Herm, T.-H. Bae, J. R. Long, Chem. Rev.2012, 112, 724.

3. S. Qiu, M. Xue, G. Zhu, Chem. Soc. Rev.2014, 43, 6116.

4. J. Y. Lee, O. K. Farha, J. Roberts, K. A. Scheidt, S. T. Nguyen, J. T. Hupp, Chem. Soc. Rev.2009, 38, 1450.

5. J. Heine, M.-B. Klaus, Chem. Soc. Rev.2013, 42, 9232.

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