Synthesis and structural characterization of two coordination polymers constructed by bis(4-(1H-imidazol-1-yl)phenyl)methanone and 5-(tert-butyl)isophthalate ligands-Reference-Cited by-同舟云学术

Synthesis and structural characterization of two coordination polymers constructed by bis(4-(1H-imidazol-1-yl)phenyl)methanone and 5-(tert-butyl)isophthalate ligands

Published:2019-01-31 Issue:3 Volume:74 Page:261-265
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Wang Gao-Feng¹,Sun Shu-Wen²,Wang Wei-Bing²,Sun Hong²,Song Shao-Fei²

Affiliation:

1. Department of Applied Chemistry , Yuncheng University , Yuncheng 044000 , P.R. China , e-mail:

2. Department of Applied Chemistry , Yuncheng University , Yuncheng 044000 , P.R. China

Abstract

Abstract Two coordination polymers, {[Co(bipmo)(tbip)]·3H2O} n (1) and {[Cd(bipmo)(tbip)]·3H2O} n (2) (bipmo=bis(4-(1H-imidazol-1-yl)phenyl)methanone, H2tbip=5-tert-butylisophthalic acid), were synthesized by solvothermal methods and structurally characterized by elemental analyses, infrared spectroscopy, and single-crystal X-ray diffraction. The results from single-crystal X-ray diffraction data indicate that the solid state structures of 1 and 2 consist of metal-aromatic carboxylate layers, which are pillared by weak interactions to generate a three-dimensional network. The topological structures of 1 and 2 are uninodal nets based on 3-connected nodes with the Schläfli symbol of {63}.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2018-0197/pdf

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