Cationic tri(ferrocenecarbonitrile)silver(I)-Reference-Cited by-同舟云学术

Cationic tri(ferrocenecarbonitrile)silver(I)

Published:2018-08-30 Issue:11 Volume:73 Page:759-764
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Strehler Frank¹,Rüffer Tobias¹,Noll Julian¹,Schaarschmidt Dieter²,Hildebrandt Alexander¹,Lang Heinrich³

Affiliation:

1. Technische Universität Chemnitz , Faculty of Natural Sciences, Institute of Chemistry, Inorganic Chemistry , D-09107 Chemnitz , Germany

2. Universität Hamburg, Institut für Anorganische Chemie, Martin-Luther-King-Platz 6 , 20146 Hamburg , Germany

3. Technische Universität Chemnitz , Faculty of Natural Sciences, Institute of Chemistry, Inorganic Chemistry , D-09107 Chemnitz , Germany , Tel. +49 (0)371 531 21210, Fax +49 (0)371 531 21219

Abstract

Abstract The synthesis of the tri-coordinated ferrocenecarbonitrile silver(I) complex [Ag(N≡CFc)3]OTf (3) is reported. Its electrochemical behavior shows that the three ferrocenyl units are oxidized in a very close potential range. In addition, the molecular structure of 3 in the solid state is discussed, showing that silver(I) is exclusively coordinated by three ferrocenecarbonitrile molecules.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2018-0090/pdf

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