Rearrangement of 14β-Hydroxy-12β-sulfoxy-steroids to 13,17-Seco-12,17-cyclo-steroids; a 2D-NMR Analysis-Reference-Cited by-同舟云学术

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Rearrangement of 14β-Hydroxy-12β-sulfoxy-steroids to 13,17-Seco-12,17-cyclo-steroids; a 2D-NMR Analysis

Published:1985-05-01 Issue:5 Volume:40 Page:656-660
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Habermehl Gerhard G.¹,Hammann Peter E.¹

Affiliation:

1. Department of Chemistry, School of Veterinary Medicine, Bischofsholer Damm 15, D-3000 Hannover 1, West Germany

Abstract

Abstract The rearrangement of 3-oxo-14β-hydroxy-12β-methanesulfoxy-card-20(22)-enolide and 14β-hydroxy-12β-methanesulfoxy-pregnane-3,20-dione during elimination of the sulfoxygroups was studied. By means of 2D-NMR analysis the structures were determined as 13,17-seco-12,17-cyclo-steroids.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1985-0516/pdf

Cited by 7 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Steroids: physical methods;Natural Product Reports;1989

2. Eliminierungsreaktionen und Umlagerungen bei 14β-Hydroxy-12-sulfonyloxy-Steroiden;Liebigs Annalen der Chemie;1988-02-16

3. Steroids: reactions and partial syntheses;Natural Product Reports;1988

4. γgauche effects in the1H and13C NMR spectra of steroids;Magnetic Resonance in Chemistry;1988-01

5. 13C NMR spectra of 5β,14β-hydroxysteroids;Magnetic Resonance in Chemistry;1985-11

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