Affiliation:
1. Dipartimento di Scienze Chimiche dell’Universitä, Via S. Agostino 1, 1-62032 Camerino
Abstract
Abstract
In the presence of alkali and LAuCl one or two -NH - groups of a purine or pyrimidine base can be transformed into - N(AuL)- groups giving stable and soluble compounds containing one or two two-coordinated gold(I) nuclei; mononuclear LAu - Q' or binuclear LAu - Q - AuL with a monodentate Q'- or an exobidentate O-- ligand, resp. (Q'H = adenine, guanine, theobromine, theophylline, azaguanine or cytosine; QH2 - thymine or uracyl; L = triphenylphosphine)
Cited by
7 articles.
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1. A gold-197 Mössbauer investigation of C-, S-, and N-derivatives of R3PAuI;Journal of Organometallic Chemistry;1991-01
2. Reactions of chloro(triphenylphosphine)gold(I) and [µ-l,2-bis(diphenylphosphine)ethane]-bis[bromogold(I)] with oxopurine bases. Molecular and crystal structure and bonding of (theophyllinato)(triphenylphosphine)gold(I);J. Chem. Soc., Dalton Trans.;1989
3. Catenated Nitrogen Ligands Part II. Transition Metal Derivatives of Triazoles, Tetrazoles, Pentazoles, and Hexazine;Advances in Inorganic Chemistry;1988
4. The reaction of chloro(triphenylphosphine)gold(I) with 1-methylthymine;Canadian Journal of Chemistry;1987-07-01
5. Mono-, di-, and tetra-aurated derivatives of barbituric acid, including a new type of polynuclear gold compound. Crystal structure of 1,3-bis(triphenylphosphinegold)-5,5-diethylbarbituric acid;Journal of Organometallic Chemistry;1986-12