Ein isoliertes cyclisches Thioarsenat(III)-Anion. Darstellung und Struktur von (enH2)3 (As3S6)2 · 6en / An Isolated Cyclic Thioarsenate(III) Anion. Preparation and Structure of (enH2)3(As3S6)2·6en-Reference-Cited by-同舟云学术

Ein isoliertes cyclisches Thioarsenat(III)-Anion. Darstellung und Struktur von (enH2)3 (As3S6)2 · 6en / An Isolated Cyclic Thioarsenate(III) Anion. Preparation and Structure of (enH2)3(As3S6)2·6en

Published:1985-01-01 Issue:1 Volume:40 Page:19-21
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Sheldrick W. S.¹,Kaub J.¹

Affiliation:

1. Fachbereich Chemie der Universität Kaiserslautern, Erwin-Schrödinger-Straße, D-6750 Kaiserslautern

Abstract

The thioarsenate(III) (enH2)3(As3S6)2 · 6en 1 (en = ethylenediamine) has been prepared by the reaction of ethylenediamine with As2S3 and its structure established by X-ray structural analysis. 1 contains discrete cyclic As3S6 3- anions with a six-membered As3S3-ring in the chair conformation. The As atoms display a ψ-tetrahedral coordination

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1985-0106/pdf

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