Chiral Rotamers of N-(1-Indanyl)-pyridinium Salts and their Restricted Rotation Around the C(sp3)—N+(sp2) Single Bond-Reference-Cited by-同舟云学术

Chiral Rotamers of N-(1-Indanyl)-pyridinium Salts and their Restricted Rotation Around the C(sp3)—N+(sp2) Single Bond

Published:1985-11-01 Issue:11 Volume:40 Page:1555-1557
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Balaban Teodor-Silviu¹,Gheorghiu Mircea D.²,Roussel Christian³,Balaban Alexandru T.²

Affiliation:

1. The Polytechnic, Department of Organic Chemistry, Splaiul Independentei 313, 76026 Bucharest, Roumania

2. The Polytechnic, Departm ent of Organic Chemistry, Splaiul Independentei 313, 76026 Bucharest, Roumania

3. I. P. S. O. I. Centre Universitaire Saint-Jérôme, Rue Henri Poincaré, 13013 Marseille, France

Abstract

Various alkyl- or aryl-substituted N-(1-indanyl)-pyridinium perchlorates present evidence for restricted rotation around the C(sp3)-N + (sp2) single bond giving rise to chiral rotamers as shown by their 1H NMR spectra.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1985-1123/pdf

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