31P-NMR-und 57Fe-Mößbauer-spektroskopische Untersuchungen an Pentacyano(phosphan oder phosphit)ferraten(II) / 31P NMR and 57Fe Mössbauer Spectroscopic Studies on Pentacyano(phosphane or phosphite)ferrates(II)-Reference-Cited by-同舟云学术

31P-NMR-und 57Fe-Mößbauer-spektroskopische Untersuchungen an Pentacyano(phosphan oder phosphit)ferraten(II) / 31P NMR and 57Fe Mössbauer Spectroscopic Studies on Pentacyano(phosphane or phosphite)ferrates(II)

Published:1985-01-01 Issue:1 Volume:40 Page:22-25
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Inoue Hidenari¹,Sasagawa Masahiro¹,Fluck Ekkehard²

Affiliation:

1. Department of Applied Chemistry, Keio University, Yokohama 223, Japan

2. Gmelin-Institut für anorganische Chemie und Grenzgebiete der Max-Planck-Gesellschaft, Varrentrappstraße 40/42, D-6000 Frankfurt am Main 90

Abstract

The 31P{1H}NMR spectra for a series of pentacyanoferrates(II) of the type Na3[Fe(CN)5L] (L = phosphine or phosphite) have been measured. A low field chemical shift range of 48.1-88.7 ppm for phosphine complexes and of 32.5-48.4 ppm for phosphite complexes is observed when one compares free vs. coordinated ligands. The correlation between chemical shifts in the 31P NMR spectra and isomeric shifts in the Mössbauer spectra is investigated and discussed

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1985-0107/pdf

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1. Electron-transfer chain catalysis in phosphine replacement reaction: Determination of relative donor capability of arylpyridylphosphines;Inorganica Chimica Acta;2007-05

2. Mössbauer spectroscopic studies of thermal decomposition of substituted pentacyanoferrate(II) complexes;Journal of thermal analysis;1997-10

3. Mössbauer spectroscopic and thermal decomposition studies of alkylamine and nitrogen heterocyclic substituted pentacyanoferrate(II) complexes;Thermochimica Acta;1996-09

4. Characterization of Pentacyano(Phosphine or Phosphite)Ferrates (II) By31P NMR and Cyclic Voltammetry;Phosphorus, Sulfur, and Silicon and the Related Elements;1993-04

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