Affiliation:
1. Abteilung II für Anorganische Chemie im Eduard-Zintl-Institut der Technischen Hochschule Darmstadt, Hochschulstraße 4, D-6100 Darmstadt
Abstract
Ba3(AsS4)2 · 7H2O crystallizes in the monoclinic system, space group P21/c (No. 14) with a = 1275.8(4) pm, b = 1282.9(4) pm, c = 1907.7(6) pm, β = 139.5( 1)°. In the structure there are isolated AsS4
3- tetrahedra with As-S-bond lengths between 216.3 and 217.8 pm. The Ba2+ ions are coordinated by a total of 8 to 10 S2- ions and H2O molecules
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