Synthese und Kristallstruktur von 1,1,1,3,3,3-Hexafluor-2-propylamino-1-thiooxamid / Synthesis and Crystal Structure of 1,1,1,3,3,3-Hexafluoro-2-propylamino-1-thiooxamide-Reference-Cited by-同舟云学术

Synthese und Kristallstruktur von 1,1,1,3,3,3-Hexafluor-2-propylamino-1-thiooxamid / Synthesis and Crystal Structure of 1,1,1,3,3,3-Hexafluoro-2-propylamino-1-thiooxamide

Published:1985-01-01 Issue:1 Volume:40 Page:124-126
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Roesky Herbert W.¹,Hofmann Hartmut¹,Noltemeyer Mathias¹,Sheldrick George M.¹

Affiliation:

1. Institut für Anorganische Chemie der Universität Göttingen, Tammannstraße 4, D-3400 Göttingen, FRG

Abstract

Dithiooxamide 1 reacts with hexafluoroacetone 2 at room temperature to yield 1,1,1,3,3,3-hexafluoro-2-propylamino-1-thiooxamide 3 and sulfur. The modes of formation of the bis(trifluoromethyl)-methyl group from hexafluoroacetone, the migration of oxygen and the elimination of sulfur are not clear. Crystals of 3 are monoclinic, space group Cc, with a = 2865.3(13), b = 924.4(9), c = 702.9(6) pm, β = 93.3(7)°. The structure was refined to R = 0.067 from 614 reflections

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1985-0124/pdf

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