Neue Bis(phosphan)-nickel(0)-alkin-Komplexe /New Bis(phosphane)-nickel(0)-alkyne Complexes-Reference-Cited by-同舟云学术

Neue Bis(phosphan)-nickel(0)-alkin-Komplexe /New Bis(phosphane)-nickel(0)-alkyne Complexes

Published:1985-02-01 Issue:2 Volume:40 Page:199-209
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Pörschke Klaus R.¹,Mynott Richard¹,Angermund Klaus¹,Krüger Carl¹

Affiliation:

1. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-4330 Mülheim a.d. Ruhr

Abstract

Abstract (Me3P)2Ni(C2H4) (5) and (dmpe) 2Ni2(C2H4)3 (6) react with various alkynes including ethyne (acetylene) and 1-alkynes to form the crystalline compounds (Me3P)2Ni(C2RR′), (dmpe)Ni(C2RR′), and (dmpe)2Ni2(C2R2)2 (R.R′ = H, Me, Ph). Structural assignments were made on the basis of 1H, 13C, and 31P NMR data. The crystal and molecular structure of (dmpe)Ni(C2Ph2) (17) has been determined by X-ray crystallography.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1985-0210/pdf

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