Affiliation:
1. Institut für Anorganische Chemie und Strukturchemie I der Universität Düsseldorf, Universitätsstraße 1, D-4000 Düsseldorf 1
Abstract
Sodium dialkylphosphite reacts with trichlorovinylbenzene to yield in an one-batch procedure 1-phenyl-1,2,2-ethanetrisphosphonic acid hexaalkyl esters. A carbanionic intermediate of an “anomalous Michaelis-Becker reaction” is deduced. Acidolysis of esters leads to the parent trisphosphonic acids. NMR param eters of this acid are strongly influenced by protolytic equilibrium.
Cited by
12 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献