Author:
Zadorozhnii Pavlo V.,Kiselev Vadym V.,Pokotylo Ihor O.,Okhtina Oxana V.,Kharchenko Aleksandr V.
Abstract
Abstract
The mass spectrometric fragmentation of 6-(4-chlorophenyl)-N-aryl-4-(trichloromethyl)-4H-1,3,5-oxadiazin-2-amines was studied under fast-atom bombardment (FAB) conditions. To simplify the interpretation of the mass spectra, a number of new 4H-1,3,5-oxadiazine derivatives containing polyisotopic elements (Cl and Br) in the arylamine substituent were synthesized. It was shown that fragmentation occurs in two main patterns.
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1. Synthesis of
N
-(1-((1
H
-perimidin-2-yl)amino)-2,2,2-trichloroethyl)carboxamides based on
N
-(2,2,2-trichloro-1-isothiocyanatoethyl)carboxamides;Synthetic Communications;2024-08-13
2. Synthesis of 6‐R‐N‐aryl‐4‐(trichloromethyl)‐4H‐1,3,5‐oxadiazin‐2‐amines based on N‐(2,2,2‐trichloro‐1‐(3‐R‐thioureido)ethyl)carboxamides: Their spectral characteristics and molecular structure;Journal of Heterocyclic Chemistry;2024-07-10
3. Synthesis, spectral characteristics and molecular structure of N-(2,2,2-trichloro-1-(hydrazinecarbothioamido)ethyl)carboxamides;Chemical Data Collections;2024-06
4. Synthesis of (Z)-N,3-dicyclohexyl-6-substituted-4-(trichloromethyl)-3,4-dihydro-2H-1,3,5-oxadiazin-2-imines via [4 + 2] hetero Diels-Alder reaction: Their spectral characteristics and molecular structure;Chemical Data Collections;2023-12
5. Synthesis, Spectral Characteristics, and Molecular Docking Studies of 2-(2,4-Dichlorophenoxy)-N-(2,2,2-trichloro-1-(3-arylthioureido)ethyl)acetamide;The 4th International Electronic Conference on Applied Sciences;2023-10-26