Comparison of ESR Spectra of Two Cu(II) Salts in Some Amide Solutions
Author:
Robers B.1,
Stockhausen M.1
Affiliation:
1. Institut für Physikalische Chemie der Universität Münster, D-48149 Münster (Germany)
Abstract
Abstract
X-band ESR spectra of liquid solutions of Cu(II)nitrate and Cu(II)chloride in N-methyl-formamide and four N,N-disubstituted amides are reported and discussed with respect to the occurrence of ion pairs or higher ionic aggregations. Nitrate solutions allow to distinguish two complex types of moderate asymmetry at most. Chloride solutions indicate a succession of at least three complex types with strongly increasing asymmetry.
Publisher
Walter de Gruyter GmbH
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics