Thermodynamic Excess Functions for Quasiternary Solid Solutions of Type M(X,Y,Z) I. The System Pb (S,Te,Se)

Abstract

Abstract The excess free enthalpy of quasiternary systems of type M (X, Y, Z) with two sublattices, a mixed one (X, Y,Z) and a pure one (M), will be described in two ways: (1) by the interaction parameters of the three subregularly treated quasibinary subsystems and by one ternary parameter, and (2) by the cluster energies of 10 pyramidal clusters. It is shown that, for the spinodal miscibility gap in the special system Pb (S, Te, Se), both versions yield satisfying accordance of experiments and calculated results