Metal Complexes of Biologically Important Ligands, CLXX [1]. Attachment of Unprotected Aminomonosaccharides and of 1,2-Diaminocyclohexane to Palladium(II) and Platinum(II) through Amino Acid and Peptide Residues-Reference-Cited by-同舟云学术

Metal Complexes of Biologically Important Ligands, CLXX [1]. Attachment of Unprotected Aminomonosaccharides and of 1,2-Diaminocyclohexane to Palladium(II) and Platinum(II) through Amino Acid and Peptide Residues

Published:2008-11-01 Issue:11 Volume:63 Page:1252-1256
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Ehrenstorfer-Schäfers Eva-Maria¹,Altman Janina²,Beck Wolfgang²

Affiliation:

1. Department Chemie und Biochemie, Ludwig-Maximilians-Universität München, Butenandtstraße 5 – 13, 81377 München, Germany

2. Department Chemie und Biochemie, Ludwig-Maximilians-Universität München, Butenandtstraße 5 - 13, 81377 München, Germany

Abstract

Abstract The reactions of unprotected D-glucosamine with N-coordinated, activated amino acid ester ligands (glycine, diglycine, histidine) of platinum(II) and palladium(II) complexes afford cis- and trans- Cl2Pt(NH2CH2CONHR), trans-Cl2Pt(NH2CH2CONHCH2CONHR)2 and Cl2Pd(histNHR)2 (R = sugar residue) as products. 1,2-Diaminocyclohexane reacts with the activated esters of cis-Cl2Pt- (NH2CH2COOH)2, cis-Cl2Pt(triglyOH)2, cis-Cl2Pt(metOH) and cis-Cl2Pd(histOH) to give dinuclear complexes Cl2Pt[(gly)nNHC6H10NH(gly)n]2PtCl2 (n = 1, 3), Cl2Pt(methNHC6H10NHmeth)- PtCl2 and Cl2Pd(histNHC6H10NHhist)PdCl2.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2008-1102/pdf

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