Some Unsymmetrical Metal 1,2-Dithiolenes Based on Palladium, Platinum and Gold

Author:

Papavassiliou George C.1,Anyfantis George C.1,Terzis Aris2,Psycharis Vassilis2,Kyritsis Panayotis3,Paraskevopoulou Patrina3

Affiliation:

1. Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, 48, Vassileos Constantinou Ave., Athens 116 35, Greece

2. Institute of Materials Science, NCSR, Demokritos, Athens 153 10, Greece

3. Department of Inorganic Chemistry, Faculty of Chemistry, University of Athens, Panepistimioupoli Zografou 157 71, Athens, Greece

Abstract

The unsymmetrical complexes Pd(dpedt)(dddt), Pt(dpedt)(dddt), Pd(dpedt)(dmit), and Au(dpedt)- (dddt) (where dpedt is diphenyl-ethylenedithiolate, dddt is 5,6-dihydro-1,4-dithin-2,3-dithiolate and dmit is 1,3-dithiol-2-thione-4,5-dithiolate) were prepared and characterized. The study of their chemical and electrochemical behavior showed that they are stable in air and could be candidate materials for fabrication of field-effect transistors and other devices.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

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