Synergistic effects of hierarchical porous structure, acidity and nickel metal for hydro-liquefaction of thermal extracts from lignite over Ni/ZSM-5-Reference-Cited by-同舟云学术

Synergistic effects of hierarchical porous structure, acidity and nickel metal for hydro-liquefaction of thermal extracts from lignite over Ni/ZSM-5

Published:2022-05-31 Issue:12 Volume:20 Page:1329-1339
ISSN:1542-6580
Container-title:International Journal of Chemical Reactor Engineering
language:en
Short-container-title:

Author:

Li Ning¹,Ren Shibiao¹,Jiang Tao¹,Yan Jingchong¹,Wang Zhicai¹,Lei Zhiping¹,Pan Chunxiu¹,Kang Shigang¹,Li Zhanku¹,Shui Hengfu¹

Affiliation:

1. School of Chemistry and Chemical Engineering, Anhui Province Key Laboratory of Coal Clean Conversion and High Valued Utilization, Anhui University of Technology , Ma’anshan , Anhui 243002 , China

Abstract

Abstract Hydro-liquefaction of the thermal extracts (HPC) from lignite was investigated over ZSM-5 and Ni/ZSM-5 with hierarchical pores or not. The thermal extracts dissolved (HPC-S) and deposited (HPC-D) at room temperature were prepared to compare their hydro-liquefaction performances. Combined to the hydrogenation properties of ZSM-5 and Ni/ZSM-5 catalysts for tetralin as a model compound, the roles of the porous structure, acidity and hydrogenation component in Ni/ZSM-5 for hydro-liquefaction of HPC were investigated. A synergy of the porous structures, nickel metal and acidity for hydro-liquefaction of HPC-S over Ni/ZSM-5 catalyst was found. During hydro-liquefaction, it is essential for the presence of nickel in the catalyst, since the parts of the benzene rings in HPC-S are first saturated by hydrogen under the role nickel. Then a certain acidity especially Brønsted acid is required in the catalyst to open the saturated benzene rings. Since there are the macromolecular organic compounds in the HPC-S, the hierarchical porous structures are required in the catalyst to promote the hydro-liquefaction performance due to their improvement on the mass transfer diffusion efficiency.

Funder

National Natural Science Foundation of China

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering

Link

https://www.degruyter.com/document/doi/10.1515/ijcre-2021-0296/pdf

Reference37 articles.

1. Almulla, F. M., S. A. Ali, M. R. Aldossary, E. I. Alnaimi, A. B. Jumah, and A. A. Garforth. 2020. “Transalkylation of 1,2,4-Trimethylbenzene with Toluene Over Large Pore Zeolites: Role of Pore Structure and Acidity.” Applied Catalysis A: General 608: 117886, https://doi.org/10.1016/j.apcata.2020.117886.

2. Anggoro, D. D., H. Oktavianty, S. B. Sasongko, and L. Buchori. 2020. “Effect of Dealumination on the Acidity of Zeolite Y and the Yield of Glycerol Mono Stearate (GMS).” Chemosphere 257: 127012, https://doi.org/10.1016/j.chemosphere.2020.127012.

3. Auepattana-aumrung, C., S. Praserthdam, S. Wannakao, B. Jongsomjit, J. Panpranot, and P. Praserthdam. 2021. “Observation of Reduction on Alkane Products in Butene Cracking Over ZSM-5 Modified with Fe, Cu, and Ni Catalysts.” Fuel 291: 120265, https://doi.org/10.1016/j.fuel.2021.120265.

4. Bi, C. Y., X. Wang, Q. You, B. Y. Liu, Z. Li, J. B. Zhang, Q. Q. Hao, M. Sun, H. Y. Chen, and X. X. Ma. 2020. “Catalytic Upgrading of Coal Pyrolysis Volatiles by Ga-Substituted Mesoporous ZSM-5.” Fuel 267: 117217, https://doi.org/10.1016/j.fuel.2020.117217.

5. Bolshakov, A., R. V. D. Poll, T. V. Bergen-Brenkman, S. C. C. Wiedemann, N. Kosinov, and E. J. M. Hensen. 2020. “Hierarchically Porous FER Zeolite Obtained via FAU Transformation for Fatty Acid Isomerization.” Applied Catalysis B: Environmental 263: 118356, https://doi.org/10.1016/j.apcatb.2019.118356.