Semiconducting nanomaterials for photocatalytic desulfurization of liquid fuel under sunlight irradiation

Abstract

Abstract Nanomaterials have fascinated the interest of researchers due to their unique electronic, optical, magnetic, and several other properties. Tin sulfide (SnS2) and Zinc oxide (ZnO) have emerged as promising materials for pharmaceutical, textile, environmental remediation, energy conversion, and storage device design. These two compounds were widely used in waste-water treatment for photocatalytic destruction of organic contaminants. However, the degradation of organic sulfur compounds in the liquid fuel desulfurization process has rarely been investigated using such materials. We hereby, present a hydrothermal method for developing the hexagonal lattice structure of SnS2 and ZnO for the deep desulfurization of model liquid fuel. These materials were further characterized through powder X-ray diffraction for phase purity and crystalline, FTIR analysis to validate functional groups, N2 adsorption-desorption isotherm to study surface properties, UV–vis diffuse reflectance spectroscopy for band gap analysis, scanning and transmission electron microscopy for morphology analysis. The optical behavior reveals that the energy gap for SnS2 and ZnO is 2.09 and 3.21 eV, respectively which corresponds to the visible light absorption range. The photocatalysis experiment was carried out in direct sunlight to degrade 10 ppm DBT in iso-octane. The obtained results show that 60% of the DBT degrade with SnS2 and 15% of the DBT degraded with ZnO in 120 min, with a first-order kinetics rate constant of 0.009 and 0.001 min−1 respectively.