Hydrodesulfurization of dibenzothiophene using NiMoWS catalysts supported on Al–Mg and Ti–Mg mixed oxides

Abstract

AbstractIn this work, two series of trimetallic NiMoW sulfide catalysts supported on Al–Mg(x) and Ti–Mg(x) mixed oxides with different content of MgO (x = 5, 10, 15 and 20 wt.% of MgO) were synthesized. The mixed oxides and catalysts were characterized by X-ray diffraction (XRD), Fourier-transform infrared (FT-IR) spectroscopy, N2 physisorption and Diffuse reflectance spectroscopy (DRS UV–Vis); and evaluated during the hydrodesulfurization (HDS) of dibenzothiophene (DBT) reaction. The NiMoW/Al–Mg catalysts showed a higher dispersion of Ni, Mo and W species than NiMoW/Ti–Mg catalysts resulting in higher catalytic activities. Catalysts with 10 wt.% of MgO showed the highest catalytic activity for both series of catalysts. Most of the synthesized catalysts exhibited higher activities than NiMoWS/Al–Ti reference catalyst. The present comparison study clearly showed that NiMoW/Al–Mg and NiMoW/Ti–Mg catalyst with 10 wt.% of MgO might be a promising and effective catalyst for the HDS-DBT reaction.