Adsorption of paratoluic acid on MIL-53 (Al) metal-organic framework, and response surface methodology optimization

Abstract

Abstract In this study, an organic metal framework adsorbent was used to remove paratoluic acid from aqueous solutions. The effect of various parameters such as pH, initial concentration of paravoluic acid, contact time, and amount of adsorbent was investigated by experimental design method. Central composite design (CCD) was used to optimize paratoluic acid uptake. Initially, MIL-53 (Al) was synthesized, and characterized by X-ray diffraction (XRD), Fourier transforms infrared spectroscopy (FTIR), spectroscopy, and thermogravimetry (TGA). The results of central composite design showed that pH is the most essential factor in the removal of paratoluic acid with MIL-53 (Al). The maximum removal efficiency of paratoluic acid by MIL-53 (Al) adsorbent is 93.67%, the optimal amount of adsorbent is 0.396 g, the optimal time is 35.67 min, the initial concentration is 11.12 mg L−1. The pH is 6.6 with the desired amount 1 is. Isothermal, and kinetic models have also examined. The maximum adsorption capacity was 132.05 (mg g−1), and the adsorption data of MIL-53 (Al) were well consistent with the quasi-second order, and Langmuir isotherm models.