Beneficiation of phosphate-siliceous slates via acetic acid

Author:

Raiymbekov Yerkebulan1ORCID,Besterekov Uilesbek1,Abdurazova Perizat1,Nazarbek Ulzhalgas1,Kambarova Galiya1,Petropavlovskiy Igor2

Affiliation:

1. Chemical Technology of Inorganic Substances , M Auezov South Kazakhstan State University , Tauke Khan, 5, 160012 Shymkent , Shymkent , Kazakhstan

2. Dmitry Mendeleev University of Chemical Technology of Russia , Moskva , Moskovskaja oblast’ , Russian Federation

Abstract

Abstract Low grade phosphate-siliceous slates dump samples (about 11.98% P2O5) from Zhanatas deposit, Karatau basin, Kazakhstan were subjected to upgrading in the present study. The suggested upgrading route was to get rid of most of the inorganic carbonates via leaching using organic acids like acetic acid. The effect of leaching temperature, dissolution time, and solid/liquid ratio were studied as the main determental working parameters. It was concluded that a concentrate product containing about 21% P2O5 was produced after leaching with acetic acid at optimum conditions: 30 C0, 15 min, and 3:1 liquid/solid ratio. The calculated apparent activation energy of the leaching process showed that the process took place in the intra-diffusion region.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering

Reference29 articles.

1. Ashraf, M. 2010. Reaction Kinetics and Mass Transfer Studies in Selective Leaching of Low-Grade Calcareous Phosphate Rock. Multan: Bahauddin Zakariya University.

2. Bakry, A. R., N. A. Abdelfattah, A. B. Farag, and A. M. Elwy. 2015. “Upgrading of Abu-Tartur Calcareous Phosphate via Selective Leaching by Organic Acids.” International Journal of Engineering Research 6: 57–64.

3. Basile, A. 2013. Acetic Acids: Chemical Properties, Production and Applications. Hauppauge, NY: Nova Biomedical, Nova Science Publishers, Inc.

4. Bulakh, A. G. 2002. General Mineralogy. Saint-Petersburg: Saint-Petersburg State University.

5. Dikusar, E. A., N. G. Kozlov, and V. I. Potkin. 2013. Soli organicheskih kislot i aminov [in Russian: Salts of Organic Acids and Amines]. Republic of Moldova: LAP Lambert Academic Publishing.

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