Conversion of elemental phosphorus under the electron beam irradiation

Author:

Tarasova Natalia1,Zanin Alexey1,Ponomarev Alexander2,Toropygin Ilya3,Krivoborodov Efrem1

Affiliation:

1. 65054 D. Mendeleev University of Chemical Technology of Russia , 125047 Moscow , Russia

2. 89105 A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences , 119071 Moscow , Russia

3. 68483 V. N. Orekhovich Research Institute of Biomedical Chemistry, Russian Academy of Sciences , 119121 Moscow , Russia

Abstract

Abstract This research article describes the results of studies of the processes occurring under the electron beam irradiation of elemental phosphorus in an aqueous medium. Comparisons of the results of white phosphorus samples irradiation using electron accelerators with different technical parameters are presented. The structure of the obtained phosphorus-containing polymers was determined using MALDI mass spectrometry and X-ray fluorescence analysis. A scheme of the formation of macroparticles in the process of irradiation of elemental phosphorus by a beam of accelerated electrons in an aqueous medium is discussed.

Funder

Russian Science Foundation

Publisher

Walter de Gruyter GmbH

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