Comprehensive evaluation of physical properties and carbon dioxide capacities of new 2-(butylamino)ethanol-based deep eutectic solvents
Author:
Nowosielski Bartosz12ORCID, Jamrógiewicz Marzena3, Cichowska-Kopczyńska Iwona4, Warmińska Dorota1
Affiliation:
1. Department of Physical Chemistry, Faculty of Chemistry , Gdańsk University of Technology , ul. Narutowicza 11/12 , 80-233 Gdańsk , Poland 2. Maritime Advanced Research Centre , Szczecińska 65 , 80-392 Gdańsk , Poland 3. Department of Physical Chemistry, Faculty of Pharmacy , Medical University of Gdańsk , Al. Gen. Hallera 107 , 80-416 Gdańsk , Poland 4. Department of Process Engineering and Chemical Technology, Faculty of Chemistry , Gdańsk University of Technology , ul. Narutowicza 11/12 , 80-233 Gdańsk , Poland
Abstract
Abstract
The aim of this research was to assess the impact of the components of alkanolamine deep eutectic solvents (DESs) on the physical properties of those DESs and their carbon dioxide capacity. To achieve this goal, novel deep eutectic solvents were synthesized by using 2-(butylamino)ethanol (BAE) as the hydrogen bond donor (HBD), along with tetrabutylammonium bromide TBAB), tetrabutylammonium chloride (TBAC), or tetraethylammonium chloride (TEAC) as the hydrogen bond acceptors (HBA) at various molar ratios (1:6, 1:8, and 1:10). To confirm the presence of hydrogen bond interactions between the components Fourier Transform Infrared Spectroscopy measurements were conducted. Furthermore, thermal properties, including melting points and thermal stability, of these deep eutectic solvents as well as key physical properties, such as density, viscosity, refractive index, and sound velocity, within the temperature range of 293.15–333.15 K and at a pressure of 0.1 MPa were examined. The effect of the molar ratio of HBA to HBD, the type of anion, and the length of the alkyl chain were studied and analysed in regard to physicochemical properties. In this work, the solubility of carbon dioxide in DESs derived from 2-(butylamino)ethanol, 3-aminopropan-1-ol (AP), and 2-(methylamino)ethanol (MAE) was measured. The highest CO2 capacity was found for TEAC:MAE 1:10 DES characterized by the shortest alkyl chain length in both HBA and HBD molecules, the highest amine content, and the lowest viscosity. Additionally, the effect of water addition on carbon dioxide solubility was explored. The results showed that the influence of water on CO2 solubility varies with the type of DES. In general, this work highlighted that DESs can serve as effective media for carbon dioxide capture, and their performance can be tailored by changing the type of hydrogen bond acceptor or donor, their molar ratio and by the addition of water.
Publisher
Walter de Gruyter GmbH
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