Preparation of polymer gel dosimeters for low gamma irradiation dose

Author:

El-Kelany Moushera A.1,Khozemy Ehab E.2ORCID,Goda Heba3,Boshra Awad 3

Affiliation:

1. Radiation Protection and Dosimetry Department , National Center for Radiation Research and Technology, Egyptian Atomic Energy Authority , Cairo , Egypt

2. Polymer Chemistry Department , National Center for Radiation Research and Technology, Egyptian Atomic Energy Authority , Cairo , Egypt

3. Chemistry Department, Faculty of Women for Arts, Science and Education , Ain Shams University , Cairo , Egypt

Abstract

Abstract In this study, two separate hydrogel dosimeters were prepared for low-dose measurement. The first system is based on Congo Red (CR) dye and a blend of natural polymers (gelatin/CMC) while the second system is based on 2,6-dichlorophenol indophenol (DCP) blue dye and a hybrid polymer blend (PVA/gelatin/CMC). The sensitivity of Congo red (CR)–(gelatin/CMC) gel dosimeter and 2, 6 – di choro phenol indophenols(DCP)-(PVA/gelatin/CMC) gel dosimetry systems were examined by studying the comparative results between the two different systems through the change in optical properties upon exposure to different gamma radiation doses, which showed the sensitivity of the second system (DCP)-(PVA/gelatin/CMC) to radiation is more than the first system(CR)–(gelatin/CMC) (CR) and (DCP)dyes have absorbance crest at 492 and 622 nm respectively. With the increase of the radiation dose, the decomposition of the dyes increases, and thus the color of the prepared hydrogel changes from orange to colorless in the case of (CR) dye at the dose (0–3.5 kGy) and from blue to colorless in the case (DCP) dye at the absorbed doses ranged from (0–1000 Gy). Dose-response curves, sensitivity, FTIR analysis, and the relative stability of the prepared hydrogel before and after irradiation were studied.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry

Reference33 articles.

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